As the code description implies the P0421 code means that the vehicle's control module has detected that the three-way catalytic converter is not working properly (is not as efficient as the factory is expecting). Replacing the oxygen (O2) sensors may sometimes fix the code, but in most cases the catalytic convert needs to be replaced to fix the problem. If the P0421 code is combined with other codes, try fixing the other codes first.
Check the 'Possible Causes' listed above. Visually inspect the related wiring harness and connectors. Check for damaged components and look for broken, bent, pushed out, or corroded connector pins.
The cost to diagnose the P0421 KIA code is 1.0 hour of labor. The diagnosis time and labor rates at auto repair shops vary depending on the location, make and model of the vehicle, and even the engine type. Most auto repair shops charge between $75 and $150 per hour.
The P0421 code is set when the Powertrain Control Module (PCM) detects rear HO2S value difference becomes closer to value of front HO2S.
The catalyst’s efficiency is demonstrated by its ability to oxidize CO and hydrocarbon emissions. The Powertrain Control Module (PCM) compares the output signals of the front and rear oxygen sensors to determine whether the output of the rear sensor is beginning to match the output of the front oxygen sensor. Air/fuel mixture compensation keeps the frequency of the front oxygen sensor high due to the changes from rich-to-lean comvustio. The catalyst causes the rear oxygen sensor to have a lower frequency. As the catalyst wears, the rear oxygen sensor’s signal trace begins to match the front oxygen sensor’s signal trace. That is because the catalyst becomes saturated with oxygen and cannot use the oxygen to convert hydrocarbon and CO into H₂O and CO₂ with the same efficiency as when it was new. A completely worn catalyst shows a 100% match between the frequency of the front and rear sensors.
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